First on the PS4 is Heavy Rain a game putting you in a number of roles as you investigate a serial killer.
Next is Absolver a third-person action/fighting game that surprises me to be on this list as it’s not even a year old yet.
On the PS3 you get platformer Rayman 3 HD and strategy game Deception IV: The Nightmare Princess.
Finally for the Vita you’ll be picking up Space Overlords (also available on the PS3 and PS4) and adventure game Zero Escape: Zero Time Dilemma.
Not a bad roundup of titles for the price of membership.